Eager to shed her goody-goody image after shooting to fame in Disney's The Princess Diaries (2001), naughty Anne went in a whole other direction in 2005 and turned from a cute girl next door into a sexy vamp who set pulses racing in theaters across the world. First up came her nude role in Brokeback Mountain where she gets naked to have sex with Jake Gyllenhaal, before she starred in the controversial Havoc, which saw her nearly raped in a long, graphic sex scene that has lingering, close-up looks at her great rack as she gets jiggy with a tattooed gangster. Anne came of age that year and after more nudity in Rachel's Getting Married (2008) long may it continue.

Rachel Getting Married (2008)

Anne is sitting nude in the tub having just been beaten up, so her sister is holding an ice-pack to her black eye and poor Anne is crying. Helpful sis is also giving her a hand shaving her pits and as she does so we can see a brief peek of nipple.

Havoc (2005)

Sexy Anne toys with a guy filming her as she reclines on the couch, pulling down her shirt straps and then tantalisingly lowering her bra so that we can see her erect nips as she rubs her left breast and moans in mock ecstasy. All the while her right hand is down the front of her jeans as she pretends to rub her clit. Then for some reason the humorless videographer asks her to cover up so they can get some proper footage. What an idiot!

Havoc (2005)

Anne is out of her depth when she finds herself at a party and agrees to sex with a greasy looking gang member. So they're snogging on a motel bed and everything's fine. She's on her back and he peels off her tiny top revealing her lovely tits which he proceeds to lick and suck. All the while his mate is fucking Anne's friend quite hard on the other bed a few metres away and Anne is feeling more and more uncomfortable. She sarts to cover her boobs up with her arms and tell her guy to stop, but he is way too horny to stop and she begs him, at which point he does the decent thing and lets her go. Traumatised Anne starts to cry with relief as she realises he could easily have raped her if he wanted and hurriedly dresses again.

Havoc (2005)

Naughty Anne is having fun with her boyfriend in his car. Sitting on him, she takes her sweater off to reveal a sexy red bra and kisses him passionately. Then she removes her bra too showing us those beautiful boobs as she gives him a blowjob while topless.

Havoc (2005)

Miss Hathaway gets herself in a catfight with another girl and amidst all the flailing arms and legs her jeans slip slightly to give us a quick peek at the top of her butt crack.

Brokeback Mountain (2005)

Cowgirl Anne takes off her shirt revealing her big breasts as she fucks gay cowboy Jake Gyllenhaal in her car. He doesn't seem too gay as he grabs her jugs and goes for it, but I guess a stunner like Anne would turn most homos straight.